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dc.contributor.authorAçık, Gökhan
dc.contributor.authorÖzen Cansoy, C. Elif
dc.contributor.authorTaşdelen, Mehmet Atilla
dc.date.accessioned2021-06-05T19:56:26Z
dc.date.available2021-06-05T19:56:26Z
dc.date.issued2019
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.urihttps://doi.org/10.1002/app.47072
dc.identifier.urihttps://hdl.handle.net/20.500.12960/268
dc.description0000-0002-7012-7029en_US
dc.description0000-0002-9427-0508en_US
dc.description0000-0002-9427-0508en_US
dc.descriptionWOS:000453845100025en_US
dc.description.abstractSynthesis of fluorine containing polypropylene (PP-F) from chlorinated polypropylene (PP-Cl) via Cu(I) catalyzed Huisgen type 1,3-dipolar cycloaddition (CuAAC) and its water repellency properties are demonstrated. Initially, clickable azido-functional polypropylene (PP-N-3) and alkyne-functionalized fluorine compound (F-Al) are independently prepared by nucleophilic substitution of PP-Cl with azidotrimethylsilane-tetrabutylammonium fluoride and esterification reactions of 2,2,3,3,4,4,5,5-octafluoro-1-pentanol with 4-pentyonic acid. The CuAAC reaction between PP-N-3 and F-Al leads to corresponding PP-F under mild conditions. The chemical structures and surface properties of desired PP-F are characterized by Fourier transform infrared, H-1-NMR, differential scanning calorimetry, scanning electron microscopy, atomic force microscope, and contact angle analyses. Based on water contact angle (WCA) measurement, it is found that both PP-Cl and PP-N-3 films have shown similar hydrophobicity, whereas the WCA of PP-F is surprisingly decreased due to the presence of ester and triazole groups coming from F-Al compound and the clicked product. This facile modification procedure could be utilized in order to alter the wetting or thermal properties of the commercial polymers for potential applications. (c) 2018 Wiley Periodicals, Inc.en_US
dc.description.sponsorshipTurkish Scientific and Technical Research Council (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [216Z060]; 1002-Short Term RAMP;D Funding Programen_US
dc.description.sponsorshipOne of the authors (G.A.) would like to acknowledge and thank Turkish Scientific and Technical Research Council (TUBITAK, Project No: 216Z060) by means of 1002-Short Term R&D Funding Program for financial support.en_US
dc.language.isoengen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal on Applied Polymer Scienceen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectFunctionalization Of Polymersen_US
dc.subjectPolyolefinsen_US
dc.subjectSurfaces And İnterfacesen_US
dc.titleSynthesis of fluorinated polypropylene using CuAAC click chemistryen_US
dc.typearticleen_US
dc.departmentFen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.departmentDenizcilik Fakültesi, Deniz Ulaştırma İşletme Mühendisliği Bölümüen_US
dc.department-temp[Acik, G.; Tasdelen, M. A.] Yalova Univ, Dept Polymer Engn, Fac Engn, TR-77100 Yalova, Turkey; [Acik, G.; cansoy, c. Elif] Piri Reis Univ, Fac Sci & Letters, TR-34940 Istanbul, Turkeyen_US
dc.contributor.institutionauthorAçık, Gökhan
dc.contributor.institutionauthorÖzen Cansoy, C. Elif
dc.identifier.doi10.1002/app.47072
dc.identifier.volume136en_US
dc.identifier.issue7en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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