dc.contributor.author | Çelik, Cumali | |
dc.contributor.author | Açık, Gökhan | |
dc.date.accessioned | 2022-02-10T08:38:10Z | |
dc.date.available | 2022-02-10T08:38:10Z | |
dc.date.issued | 2021 | en_US |
dc.identifier.citation | Celik, C., & Gokhan, A. C. İ. K. (2021). Synthesis and Characterization of Benzodioxinone-Bearing Methacrylate-Based Random Copolymer via Atom Transfer Radical Polymerization. Journal of the Turkish Chemical Society Section A: Chemistry, 8(2), p. 501-510. | en_US |
dc.identifier.issn | 2149-0120 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12960/1353 | |
dc.description.abstract | Methacrylate-benzodioxinone (BDMA) as a monomer was firstly synthesized and then copolymerized with methyl methacrylate and 2-hydroxyethyl methacrylate via atom transfer radical polymerization (ATRP) in the presence of CuCl/pentamethyldiethylene triamine (PMDETA) catalytic system using ethyl 2-bromopropionate (EtBrP) as an initiator. Successful formation of the block copolymer was also confirmed in detail by proton nuclear magnetic resonance spectroscopy (1H NMR), Fourier-transform infrared spectroscopy (FT-IR), and gel permeation chromatography (GPC) appropriately. Secondly, photochemical acylation of obtained copolymer through hydroxyl and benzodioxinone groups led to the release of benzophenone compound and ester-linkage on the polymer backbone. The formation of ester-linkage increases the glass transition temperature and the thermal stability of the obtained copolymer. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Tübitak Dergi Park | en_US |
dc.relation.ispartof | Journal of the Turkish Chemical Society, Section A: Chemistry | en_US |
dc.relation.isversionof | 10.18596/jotcsa.879021 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Atom transfer radical polymerization | en_US |
dc.subject | Ketene chemistry | en_US |
dc.subject | Photochemical acylation | en_US |
dc.subject | Random copolymer | en_US |
dc.title | Synthesis and characterization of benzodioxinone-bearing methacrylate-based random copolymer via atom transfer radical polymerization | en_US |
dc.type | article | en_US |
dc.authorid | 0000-0002-9427-0508 | en_US |
dc.department | Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Açık, Gökhan | |
dc.identifier.volume | 8 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.startpage | 501 | en_US |
dc.identifier.endpage | 510 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |