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dc.contributor.authorKaya, İsmet
dc.contributor.authorGökpınar, Mehmet
dc.contributor.authorKamacı, Musa
dc.date.accessioned2021-06-05T19:56:20Z
dc.date.available2021-06-05T19:56:20Z
dc.date.issued2017
dc.identifier.issn1598-5032
dc.identifier.issn2092-7673
dc.identifier.urihttps://doi.org/10.1007/s13233-017-5072-2
dc.identifier.urihttps://hdl.handle.net/20.500.12960/240
dc.description0000-0001-5865-7687en_US
dc.description0000-0002-9813-2962en_US
dc.descriptionWOS:000406462000010en_US
dc.description.abstractIn this paper, a series of Schiff bases and their polyazomethine derivatives were synthesized via condensation and oxidative polycondensation reactions of 4-aminophenol with 4-isopropylbenzaldehyde or 4-t-butylbenzaldehyde. Polymerization reaction conditions for polymerization yield of polyazomethines were investigated by changing some experimental parameters such as time and temperature using different oxidants like alkaline NaOCl (30%) and air. The structural characterizations of Schiff bases and polymers were performed using FT-IR, H-1 NMR, C-13 NMR and SEC techniques. Photophysical properties were studied UV-vis and photoluminescence spectroscopies. Electrochemical properties were also investigated cyclic voltammetry (CV) and electrochemical band gaps determined in the range 1.73 to 2.63 eV. Thermal properties of the compounds were investigated using TG-DTA and DSC techniques and char residue at 1000 degrees C determined between 3-6% and 39-34% for Schiff bases and polyazomethines, respectively. Moreover, conductivity measurements were done using four-point probe technique at both doped with iodine vapor and un-doped state.en_US
dc.language.isoengen_US
dc.publisherSpringeren_US
dc.relation.ispartofMacromolecular Researchen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolyazomethineen_US
dc.subjectSchiff Baseen_US
dc.subjectReaction Conditionsen_US
dc.subjectConductivityen_US
dc.subjectThermal Propertiesen_US
dc.titleReaction Conditions, Photophysical, Electrochemical, Conductivity, and Thermal Properties of Polyazomethinesen_US
dc.typearticleen_US
dc.departmentFen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.department-temp[Kaya, Ismet; Gokpinar, Mehmet; Kamaci, Musa] canakkale Onsekiz Mart Univ, Fac Sci & Arts, Dept chem, Polymer Synth & Anal Lab, TR-17020 canakkale, Turkey; [Kamaci, Musa] Piri Reis Univ, Fac Sci & Arts, Dept chem, TR-34940 Istanbul, Turkeyen_US
dc.contributor.institutionauthorKamacı, Musa
dc.identifier.doi10.1007/s13233-017-5072-2
dc.identifier.volume25en_US
dc.identifier.issue7en_US
dc.identifier.startpage739en_US
dc.identifier.endpage748en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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